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Thanks all. Non-specialist's question just to eliminate the hex thing: if the CH circuit is isolated (using lever valves) but the HW is still operating normally and there's no pressure loss (remained constant for 8 hrs overnight) , does that eliminate the heat exchanger 100%? The PRV outlet is dry (as is the wall by the pipe), and no loss of heat/pressure when it's HW-only operation
Thanks for eliminating the PRV outlet because I've lost count of the times people have told me "It's definitely not that" and that's exactly what it turned out to be!