I think my concern is, like Rob Foster's that the water is being stored in the danger band for Legionnaire's. If it were always at 60°C then I would be happy with it, but if it sometimes sits at 40°C, as it well may, then precautions are needed.
Feeding a combi boiler is all well and good (I think solar systems often do this and the pre-heat cylinder is heated and held above 60° once a week to kill germs), but if the water simply passes through the compost pre-heat then the water would only be heated to 60°C briefly (if at all) as it passes through the boiler heat exchanger, and I think it takes an hour to kill it off at 60°C.
Possibly the compost coil water could be pumped through a plate heat exchanger that could be used either directly to heat the mains water feeding the bath, or to pre-heat the boiler. In this way, none of the water that is being stored at a dubious temperature ever comes through a tap.
FWIW, if this hippy system works and can be incorporated safely into the domestic system, then I for one think it's a great idea.