That other 18L EV has got nothing to do with the heating system, you have a unvented HW cylinder and that 18L EV is to take its expansion, are you sure its not a PRV (expansion valve or main TPRV) from this system that's lifting?.
Its unlikely that the boiler PRV is lifting if the boiler pressure is not exceeding say 2.8/3.0bar.
Even though you have established that the 12L EVs diaphragm hasn't failed the precharge pressure should still be checked as the boiler PRV will lift if this precharge pressure has fallen from 1.0bar to 0.31bar, filling pressure 1.0bar. OR (will lift) if the precharge pressure is correct at 1.0bar but the filling pressure is 1.5bar. So requires system drain down, also the boiler pressure gauge may be faulty, if not and PRV is lifting at < 2.8bar then PRV needs renewing.
Its unlikely that the boiler PRV is lifting if the boiler pressure is not exceeding say 2.8/3.0bar.
Even though you have established that the 12L EVs diaphragm hasn't failed the precharge pressure should still be checked as the boiler PRV will lift if this precharge pressure has fallen from 1.0bar to 0.31bar, filling pressure 1.0bar. OR (will lift) if the precharge pressure is correct at 1.0bar but the filling pressure is 1.5bar. So requires system drain down, also the boiler pressure gauge may be faulty, if not and PRV is lifting at < 2.8bar then PRV needs renewing.