Glad to hear, Ben, that you are back in form again,
Regarding that pesky K3, Renewing the cast iron rads should help but I feel that installing a UPS3 pump would improve the flow considerably as you have established that the rad does, more or less, emit its rated output when running on its own since the boiler doesn't cycle on/off.
The UPS3 is a giant of a pump even though a "6M"(6.4) pump like the UPS2, (6.2M) see below.
The other alternative is to install a low loss header, LLH, where one pump deals with the boiler heat exchanger pressure loss and the other pump deals with the rads/system losses.
Regarding that pesky K3, Renewing the cast iron rads should help but I feel that installing a UPS3 pump would improve the flow considerably as you have established that the rad does, more or less, emit its rated output when running on its own since the boiler doesn't cycle on/off.
The UPS3 is a giant of a pump even though a "6M"(6.4) pump like the UPS2, (6.2M) see below.
The other alternative is to install a low loss header, LLH, where one pump deals with the boiler heat exchanger pressure loss and the other pump deals with the rads/system losses.