Yes very good, in basic terms if there is a demand for hot water the boiler flow temp is ramped up to 80 degC & the heating is disconnected, as soon as the HW is satisfied & there is a demand for heating the flow temp is controlled via the W/C & the particular slope selected on the boiler sat. I use 4 as I have an old 1930's house, although I have done my best to insulate the dumb W/C would not on it's own give tight enough control (unless heating was left on) so I kept the digital stat & it all works well.
I have the HW set for 4omins before the heating is required (AM only) & timed heating morning & night. The only time there is a problem is on the odd PM heating when it is a cold winters early evening as the internal temp has dropped but the outside is still relatively warm but dropping fast. It just takes too long for the house to get to temp but it isn't a problem we just move the boiler stat up to increase the water temp, as the boiler is in the kitchen this isn't a problem.
For what the W/C kit cost it was a no brainer to go with it.
If you have 2No. cylinders it could still be made to work by using a small 240V relay so if there is a demand from either the satisfied from the stats is only allow on to 5 when both cylinders are up to temp.
If you need any help with that let me know.